Product ID:ECCOFOAM FPH
MSDS Date:02/18/1993
FSC:5970
NIIN:00-768-0527
Kit Part:Y
MSDS Number: CBQLK

EMERSON & CUMING INC

77 DRAGON COURT
WOBURN, MA 01888
US

Emergency Phone: 617-935-4850

Info Phone: 617-828-3300

Preparer: DAVID HAAS

Cage: 0VVR7

EMERSON & CUMING INC

WOBURN, MA 01888 US

Telephone: 617-935-4850;617-938-8630

Cage: 0VVR7

TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)

CAS: 584-84-9

RTECS: CZ6300000

Fraction By Weight: 55-65%

OSHA PEL C,0.02 PPM/0.02 STEL

ACGIH TLV: 0.005PPM/0.02STEL;93

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TOLUENE DIISOCYANATE (TDI PREPOLYMERS)

Fraction By Weight: 35-45%

PIGMENT

Fraction By Weight: <0.1%

LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE SEVERE, REVERSIBLE EYE
IRRITATION. SKIN:MAY CAUSE SKIN IRRITATION. PROLONGED CONTACT MAY
CAUSE DERMATITIS. INHALATION:MAY CAUSE RESPIRATORY SENSITIZATION
RESPONSES IN SUSCEPTIBLE INDIVID UALS CAUSING ASTHMA-LIKE SYMPTOMS.
INGESTION:HARMFUL IF SWALLOWED. CHRONIC-
Explanation of Carcinogenicity:CONTAINS TOLUENE DIISOCYANATE. SEE THE
INDIVIDUAL IARC & NTP REPORTS FOR DETAILS OF CARCINOGENICITY.
Effects of Overexposure:SKIN-SYMPTOMS MAY INCLUDE RASH, ITCHING, HIVES,
REDDENING, OR SWELLING OF THE EXTREMITIES. INHALATION-SYMPTOMS MAY
INCLUDE TIGHTNESS OF THE CHEST, ASTHMA-LIKE SYMPTOMS, RESPIRATORY
DISTRESS; SYMPTOMS MAY BE DELAYED.
Medical Cond Aggravated by Exposure:PERSONS W/ASTHMA-TYPE CONDITIONS,
CHRONIC BRONCHITIS, OTHER CHRONIC RESPIRATORY DISEASES OR RECURRENT
SKIN EDEMA OR SENSITIZATION SHOULD BE EXCLUDED FROM WORKING
W/ISOCYANATES.

First Aid:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL ATTENTION.
EYE:FLUSH W/WATER FOR 15 MIN. SKIN:REMOVE CONTAMINATED CLOTHING &
LAUNDER BEFORE REUSE. FLUSH SKIN W/WATER THEN WASH W/SOAP & WATER.
INHALED :REMOVE FROM EXPOSURE. AID OR RESTORE BREATHING AS NEEDED.
INGESTED:DO NOT INDUCE VOMITING. GIVE 1-2 GLASSES OF MILK OR WATER
TO DRINK. GET IMMEDIATE MEDICAL ATTENTION. NOTHING BY MOUTH IF
UNCONSCIOUS

Flash Point:270F,132C
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
AVOID USING DIRECT STREAMS OF WATER; FROTHING MAY OCCUR.
Fire Fighting Procedures:FIREFIGHTERS & RESCUE PERSONNEL SHOULD WEAR
POSITIVE PRESSURE SCBA & FULL PROTECTIVE EQUIPMENT. COOL EXPOSED
CONTAINERS W/WATER TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC. CLOSED CONTAINERS MAY VIOLENTLY RUPTURE UNDER FIRE
CONDITIONS. IF LARGE FIRE, EVACUATE & FIGHT FROM DISTANCE

Spill Release Procedures:ACTIVATE ALL EXHAUST VENTILATION IN THE
IMMEDIATE AREA. WIPE UP, OR ABSORB SPILLED MATERIAL W/VERMICULITE
OR OTHER SIMILIAR MATERIAL. WASH AREA W/SOAPY WATER & ALLOW TO
PLOYMERIZE. COLLECT ABSORBED WA STE & RINSES IN APPROPIATE WASTE
CONTAINERS.
Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS.

Handling and Storage Precautions:STORE IN A TIGHTLY SEALED COTAINER AT
ROOM TEMPERATURE. PROVIDE PROPER VENTILATION. KEEP BLANKETED IN
NITROGEN TO RETARD POLYMERIZATION.
Other Precautions:KEEP AWAY FROM OPEN FLAMES AND HEAT SOURCES. CONSULT
THE PRODUCT TECHNICAL BULLETIN FOR DETAILING STORAGE INFORMATION.

Respiratory Protection:USE AN APPROPIATE, PROPERLY FITTED RESPIRATOR IF
EXPOSURE EXCEED PEL/TLV VALUES. THE TYPE OF RESPIRATORY PROTECTION
SELECTED WILL DEPEND ON THE CONDITIONS OF USE. OBSERVE OSHA
REGULATION 29CFR1910.134 ON RESPIRATORY PROTECTION.
Ventilation:PROVIDE EFFECTIVE MECHANICAL EXHAUST VENTILATION TO DRAW
VAPORS, MISTS OR FUMES AWAY FROM THE WORKER/PREVENT INHALATION.
Protective Gloves:WEAR APPROPIATE PROTECTIVE GLOVES
Eye Protection:SPLASH-PROOF GOGGLES OR FACE SHIELD
Other Protective Equipment:CHEMICAL-RESISTANT APRON & ADDITIONAL
IMPERVIOUS CLOTHING TO PREVENT SKIN CONTACT. EYE WASH & SAFETY
SHOWER, A MUST!
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EMPLOYEES MUST BE PORPERLY TRAINED IN SAFE HANDLING OF THIS PRODUCT
PRIOR TO USE.

HCC:T3
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:ND
Vapor Pres:NEGLIGIBLE
Vapor Density:NA
Spec Gravity:1.12
Solubility in Water:REACTS WITH WATER.
Appearance and Odor:RED LIQUID, SHARP ODOR.
Percent Volatiles by Volume:ND

Stability Indicator/Materials to Avoid:YES
STRONG OXIDERS, ACIDS, BASES; UNCONTROLLED MIXING W/AMINES, WATER,
POLYOLS OR ALCOHOLS MAY CAUSE HAZARDOUS POLYMERIZATIN
Stability Condition to Avoid:OPEN FLAME OR HEAT SOURCES, UNCONTROLLED
MIXING WITH CURING AGENTS OR EXPOSURE TO INCOMPATIBLE SUBSTANCES.
Hazardous Decomposition Products:OXIDES OF CARBON, ISOCYANATES, ORGANIC
ACIDS, & ALDEHYDES, TRACES OF CYANIDE & OTHER ORGANIC SUBSTANCES
FROM COMBUSTION.
Conditions to Avoid Polymerization:CONTAMINATION FROM INCOMPATIBLES,
UNCONTROLLED MIXING, AVOID STORAGE IN OPEN CONTAINERS, MAY LEAD TO
MIXTURE ABSORPTION.

Waste Disposal Methods:KEEP CONTAINERS LOOSELY SEALED IN VENTILATED
AREA FOR 24-48 HOURS. DISPOSE OF I/A/W LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.